|Mineralisation of atmospheric aerosol particles and further analysis of trace elements by inductively coupled plasma-optical emission spectrometry |
Auteur(s): Dufour A., Migon Christophe
(Article) Publié: -Methodsx, vol. 4 p.191-198 (2017)
Ref HAL: 01551606_v1
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Several protocols using different treatments (various mixtures of acids at different temperatures for mineralisation) or using several analysis instrumentations were tested with the aim to define the method allowing the analysis of some groups of elements. This study proposes a protocol of sample treatment and analysis permitting in a single batch the determination of 16 elements (Al, As, Ba, Cd, Co, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, Ti, V and Zn) with different chemical features such as volatile or refractory trace elements. This method is specifically adapted to chemical matrices found in unpolluted to moderately polluted atmospheric aerosol samples. Aerosol samples were digested using a mixture aqua regia/hydrofluoric acid at 130 °C during 2 h, and were then analysed with specifically tuned inductively coupled plasma-optical emission spectrometry.